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Chemical And Ionic Equilibrium MCQs with Explanations

Practice high-yield Chemistry & Applied Chemical Sciences MCQs on Chemical And Ionic Equilibrium with worked academic solutions for MDCAT, CSS, PMS, PPSC, FPSC.

Questions
18
Difficulty Level
Exam-Level
Target Exams
MDCAT, CSS, PMS...
Estimated Time
22 mins
Exam-Level MDCAT CSS PMS PPSC FPSC
Verified for Commission Syllabus • Oct 14, 2026
18

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Question 1 of 18
★ MDCAT ★ CSS

In the mixture obtained by mixing 25.0 mL × 1.2 × 10 -3 MMnCl 2 and 35.0 mL of 6.0 × 10 -4 M KCl solution, the concentration (M) of Mn 2+ , K + and CI - ions respectively are

Question 2 of 18
★ MDCAT ★ CSS

An aqueous solution containing m moles of non-volatile solute freezes at -0.186°C. The elevation in the boiling point of the same aqueous solution (K f = 1.86°, K b = 0.512°) would be

Question 3 of 18
★ MDCAT ★ CSS

Among the following, the equilibrium which is not affected by an increase in pressure is

Question 4 of 18
★ MDCAT ★ CSS

The number of degrees of freedom for a system consisting of NaCl(s), Na + (aq) and Cl - (aq) at equilibrium is

Question 5 of 18
★ MDCAT ★ CSS

As per the kinetic theory of ideal gases, which of the following statements is not correct?

Question 6 of 18
★ MDCAT ★ CSS

The number of degrees of freedom of a system consisting of solid sucrose in equilibrium with an aqueous solution of sucrose is

Question 7 of 18
★ MDCAT ★ CSS

For an ideal gas,

Question 8 of 18
★ MDCAT ★ CSS

If a gas obeys equation of state p(V - nb) = nRT, the ratio $$\frac{{\left( {{C_p} - {C_V}} \right)}}{{{{\left( {{C_p} - {C_V}} \right)}_{{\text{ideal}}}}}}$$ is

Question 9 of 18
★ MDCAT ★ CSS

The internal pressure of a van der Waals gas is

Question 10 of 18
★ MDCAT ★ CSS

Under the equilibrium conditions for the reaction, C(s) + CO 2 (g) $$ \rightleftharpoons $$ 2CO(g), the total pressure is 12 atm. The value of K p is

Question 11 of 18
★ MDCAT ★ CSS

According to the Ehrenfest classification of phase transition the above diagram refers to

Question 12 of 18
★ MDCAT ★ CSS

For 1 mol of a monoatomic ideal gas, the relation between pressure (p), volume (V) and average molecular kinetic energy $$\left( {\overline \varepsilon } \right)$$ is

Question 13 of 18
★ MDCAT ★ CSS

For the pair of reactions given below, (i) N 2 (g) + 3H 2 (g) $$ \rightleftharpoons $$ 2NH 3 (g) (ii) $$\frac{1}{2}$$N 2 (g) + $$\frac{3}{2}$$H 2 (g) $$ \rightleftharpoons $$ NH 3 (g) If at a particular temperature, K p1 and K p2 are the equilibrium constants for reactions (i) and (ii) respectively then

Question 14 of 18
★ MDCAT ★ CSS

The Bronsted acidity of boron hydrides follows the order

Question 15 of 18
★ MDCAT ★ CSS

The pH of buffer solution containing 4 × 10 -3 and 0.4 moles of acetic acid (pK a = 4.76) and sodium acetate respectively will be

Question 16 of 18
★ MDCAT ★ CSS

The freezing point constant for water is 1.86 K (mol/kg) -1 . The freezing point when 0.01 mol glucose is added to 1 kg water is

Question 17 of 18
★ MDCAT ★ CSS

On the pressure-temperature diagram for a one-component system, the point where the solid-liquid and the liquid-gas curves intersect is

Question 18 of 18
★ MDCAT ★ CSS

The triple point for water is

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In competitive commission exams (FPSC, PPSC, KPPSC, SPSC, CSS, PMS), questions are frequently phrased with distractor options designed to catch rote learners. Whenever you answer an MCQ, read the Detailed Academic Explanation and Conceptual Anchor to understand why the remaining options are incorrect.

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