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Chemical Bonding And Molecular Structure — Part 1 MCQs with Explanations

Practice high-yield Chemistry & Applied Chemical Sciences MCQs on Chemical Bonding And Molecular Structure — Part 1 with worked academic solutions for MDCAT, CSS, PMS, PPSC, FPSC.

Questions
40
Difficulty Level
Exam-Level
Target Exams
MDCAT, CSS, PMS...
Estimated Time
48 mins
Exam-Level MDCAT CSS PMS PPSC FPSC
Verified for Commission Syllabus • Oct 14, 2026
40

Verified Practice Questions

Interactive test mode with detailed academic worked solutions

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Question 1 of 40
★ MDCAT ★ CSS

Which of the following species has two non-bonded electron pairs on the central atom?

Question 2 of 40
★ MDCAT ★ CSS

The spinels CoFe 2 O 4 and FeFe 2 O 4 respectively are

Question 3 of 40
★ MDCAT ★ CSS

The arrangement of sulphur in zinc blende and wurtzite structures, respectively are

Question 4 of 40
★ MDCAT ★ CSS

The point group of NSF 3 is

Question 5 of 40
★ MDCAT ★ CSS

According to MO theory for the atomic species C 2

Question 6 of 40
★ MDCAT ★ CSS

If the dipole moment of HCI is 1.08 D and the bond distance is 1.27 \[{\rm{\dot A}}\], the partial charge on hydrogen and chlorine, respectively are

Question 7 of 40
★ MDCAT ★ CSS

The geometry around the central atom in CIF 4 + is

Question 8 of 40
★ MDCAT ★ CSS

The highest occupied molecular orbital of HF is

Question 9 of 40
★ MDCAT ★ CSS

The structures of N(CH 3 ) 3 and N(SiH 3 ) 3 respectively are

Question 10 of 40
★ MDCAT ★ CSS

According to VSEPR model, the shape of [XeOF 5 ] - is

Question 11 of 40
★ MDCAT ★ CSS

The incorrect statement for solid sodium chlo;ride is that

Question 12 of 40
★ MDCAT ★ CSS

The xenon compounds that are isostructural with $${\bf{IBr}}_2^ - $$ and $${\bf{BrO}}_3^ - $$ respectively are

Question 13 of 40
★ MDCAT ★ CSS

CaTiO 3 has a perovskite crystal structure. The coordination number of titanium in CaTiO 3 is

Question 14 of 40
★ MDCAT ★ CSS

According to VSEPR theory, the shapes of [SF 2 Cl] + and [S 2 O 4 ] 2- should be

Question 15 of 40
★ MDCAT ★ CSS

Fe 3 O 4 and Co 3 O 4 are metal oxides having spinel structure. Considering their CFSFs, the correct statement regarding their structure is

Question 16 of 40
★ MDCAT ★ CSS

The band structure in an n-type semiconductor is

Question 17 of 40
★ MDCAT ★ CSS

[XeO 6 ] 4- is octahedral whereas XeF 6 is a disordered one, because

Question 18 of 40
★ MDCAT ★ CSS

Band theory predicts that magnesium is an insulator. However, in practice it acts as a conductor due to

Question 19 of 40
★ MDCAT ★ CSS

Which of the following statements about the molecule NOCl is correct?

Question 20 of 40
★ MDCAT ★ CSS

Among the following, the isoelectronic and isostructural pair is

Question 21 of 40
★ MDCAT ★ CSS

The species which has a square planar structure is

Question 22 of 40
★ MDCAT ★ CSS

The hybrid orbitals used by bromine atom in BrF 3 are

Question 23 of 40
★ MDCAT ★ CSS

The symmetry elements that are present in BF 3 are

Question 24 of 40
★ MDCAT ★ CSS

The symmetry point group of the BF 3 molecule is

Question 25 of 40
★ MDCAT ★ CSS

Icosahedral structure is generally exhibited by

Question 26 of 40
★ MDCAT ★ CSS

On the basis of LCAO-MO theory, the magnetic characteristics of N 2 and $${\text{N}}_2^ + $$ are

Question 27 of 40
★ MDCAT ★ CSS

The point group of CIF 3 molecule and its corresponding number of irreducible representations are respectively

Question 28 of 40
★ MDCAT ★ CSS

The crystal structure of Pb 3 O 4 contains

Question 29 of 40
★ MDCAT ★ CSS

The ground state term symbols for high spin d 5 s 1 and d 5 configurations, respectively are

Question 30 of 40
★ MDCAT ★ CSS

The bond angle of Cl 2 O is

Question 31 of 40
★ MDCAT ★ CSS

The shape of the molecule XeO 2 F 2 is

Question 32 of 40
★ MDCAT ★ CSS

The number of manganese ions in tetrahedral and octahedral sites, respectively in Mn 3 O 4 are

Question 33 of 40
★ MDCAT ★ CSS

NaCI is crystallized by slow evaporation of its aqueous solution at room temperature. The correct statement is

Question 34 of 40
★ MDCAT ★ CSS

Among the following molecules, the shortest bond length is to be found in

Question 35 of 40
★ MDCAT ★ CSS

The ground state term for V 3+ ion is

Question 36 of 40
★ MDCAT ★ CSS

The coordination number of the Ba 2+ ions in barium fluoride is 8. The coordination number of the fluoride ion is

Question 37 of 40
★ MDCAT ★ CSS

The compound (SiH 3 ) 3 N is expected to be

Question 38 of 40
★ MDCAT ★ CSS

The atomic radius (in cm) of an element with a body centred cubic unit cell of volume 75.8 cm 3 mol -1 , molecular weight 137.3 and density 3.62 g cm -3 is

Question 39 of 40
★ MDCAT ★ CSS

Among the compounds Fe 3 O 4 , NiFe 2 O 4 and Mn 3 O 4

Question 40 of 40
★ MDCAT ★ CSS

The structures of O 3 and $${\text{N}}_3^ - $$ are

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In competitive commission exams (FPSC, PPSC, KPPSC, SPSC, CSS, PMS), questions are frequently phrased with distractor options designed to catch rote learners. Whenever you answer an MCQ, read the Detailed Academic Explanation and Conceptual Anchor to understand why the remaining options are incorrect.

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